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Isothermal Age-hardening Behavior of a High Carat Au-Zn-Pt Alloy

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ÀÌÈñ°æ/Hee Kyung Lee ¹Ú¿µÈ¯/¹®Èñ¸¸/ÀÌÁ¤Àº/±èÇüÀÏ/Young Hwan Park/Hi Man Moon/Jung Eun Lee/Hyung Il Kim

Abstract

º» ¿¬±¸´Â Ä¡°úÁÖÁ¶¿ë °íÄ«¶óÆ® Au-Zn-Pt ÇÕ±ÝÀ» µî¿Â½Ãȿó¸®ÇÏ¿´À» ¶§, ½ÃÈ¿°æÈ­¿Í »óº¯Å¿ÍÀÇ °ü°è¸¦ Á¶»çÇϱâ À§ÇÏ¿© °æµµ½ÃÇè, X¼±È¸Àý ¿¬±¸, ÁÖ»çÀüÀÚÇö¹Ì°æ °üÂû, ÀüÀÚŽħ ¹Ì¼ÒºÐ¼® µîÀ» ½ÃÇàÇÏ¿´´Ù. º» ÇÕ±ÝÀº 800¡É¿¡¼­ ¿ëÁ¦È­Ã³¸®µÈ ÇÕ±ÝÀ» 300~400¡É
¿Âµµ±¸°£¿¡¼­ µî¿Â½Ãȿó¸®ÇÔ¿¡ µû¶ó À¯»çÇÑ ½ÃÈ¿°æÈ­ °Åµ¿À» ³ªÅ¸³»¾ú´Ù. °æµµ´Â ½ÃÈ¿°³½Ã¿Í ÇÔ²² ¼­¼­È÷ »ó½ÂÇÏ¿© ÃÖ°í °æµµ¿¡ µµ´ÞÇÏ¿´°í, ÃÖ°í °æµµ¸¦ ÀÏÁ¤±â°£ À¯ÁöÇÏ°í ³ª¼­ Á¡Â÷ ÇÏ°­ÇÏ¿´´Ù. ½ÃÈ¿ÃʱâÀÇ °æµµ »ó½ÂÀº ½Ãȿ󸮿µµ°¡ ³ôÀ»¼ö·Ï ºü¸£°Ô
³ªÅ¸³µ°í,
½ÃÈ¿½Ã°£ÀÇ ¿¬Àå¿¡ µû¸¥ °æµµ °¨¼Òµµ ½ÃÈ¿ 󸮿µµ°¡ ³ôÀ»¼ö·Ï ºü¸£°Ô ³ªÅ¸³µ´Ù. º» ÇÕ±ÝÀ» ¿ëÁ¦È­Ã³¸®ÇÏ¿© 300~400¡É¿¡¼­ µî¿Â½Ãȿó¸®ÇÏ¸é ¸é½ÉÀÔ¹æ(f.c.c.) ±¸Á¶ÀÇ Au-rich ¥á1»ó, AuCu3(L12)Çü ±ÔÄ¢»ó(f.c.c.)ÀÇ
Pt3Zn
¥á2»ó°ú f.c.c. ±¸Á¶ÀÇ Pt-rich ¥á3»óÀÇ 3»ó °øÁ¸ÀÌ ¥á1»ó, ¥á3»ó ±×¸®°í ¸é½ÉÁ¤¹æ(f.c.t.) ±¸Á¶ÀÇ AuCu I(L10)Çü ±ÔÄ¢»óÀÎ PtZn ¥â»óÀÇ 3»ó °øÁ¸À¸·Î º¯ÅÂÇÏ¿´´Ù. °æÈ­´Â ¥á2»ó¿¡¼­ ¥â»óÀ¸·ÎÀÇ
º¯Å¿¡
±âÀÎÇÑ °ÍÀ¸·Î º¸ÀÌ°í, °ú½ÃÈ¿ ¿¬È­´Â ¥á1»ó°ú ¥â»óÀ¸·Î µÈ nodule Á¶Á÷ÀÇ Á¶´ëÈ­¿¡ ±âÀÎÇÑ °ÍÀ¸·Î ÃßÁ¤µÈ´Ù.

The isothermal age-hardening bahavior of a high carat Au-Zn-Pt alloy was investigated by means of hardness test, X-ray diffraction study, microscopic observation and electron probe micro analysis. By the isothermal ageing of the solution-treated
specimen at 300~400¡É, the hardness increased slowly at the initial stage of ageing and reached a maximum hardness value and then decreased gradually for a time. The maximum hardness values at 300~400¡É was similar and suitable to use as the
crown
&
bridge. By the isothermal ageing of the solution-treated specimen at 300~400¡É, three phases of the Au-rich ¥á1 phase with a face-centered cubic structure, the Pt3Zn ¥á2 phase with an ordered
AuCu3(L12) type(f.c.c.) and the Pt-rich ¥á3 phase with face-centered cubic structure were treansformed into three phases of the ¥á1 phase, the ¥á3 phase and the PtZn ¥â phase with an ordered
AuCu
I(L10) type. The hardening seemed to be attributed to the lattice strains of the matrix resulting from the transformation of the ¥á2 phase to the ¥â phase. The overageing with softening was attributed to the coarsening of
the
nodule precipitates which seemed to be composed of the ¥â phase and ¥á1 matrix.

Å°¿öµå

gold alloy; isothermal age-hardening; phase transformation; PtZn phase; Pt3Zn phase;

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